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The Home Office does not centrally hold the information requested.
The Office for National Statistics publish data on suicide by occupation in England. The latest release can be found here: https://www.ons.gov.uk/peoplepopulationandcommunity/birthsdeathsandmarriages/deaths/datasets/suicidebyoccupationenglandsupplementarydatatables
The Home Office has not issued any guidance to police forces on the collection of statistics on the number of police officers taking their own lives.